10.2: Specific Heat
This image is of the Beehive Geyser in Yellowstone National Park. Underground water is heated by the earth’s molten core and, when sufficient pressure is built up, the water shoots out of the ground in an amazing display.
Specific Heat
When heat flows into an object, its thermal energy increases and so does its temperature. The amount of temperature increase depends on three things: 1) how much heat was added, 2) the size of the object, and 3) the material of which the object is made. When you add the same amount of heat to the same mass of different substances, the amount of temperature increase is different. Each substance has a specific heat, which is the amount of heat necessary to raise one mass unit of that substance by one temperature unit.
In the SI system, specific heat is measured in J/kg•K. (Occasionally, you may also see specific heat expressed sometimes in J/g•K). The specific heat of aluminum is 903 J/kg•K. Therefore, it requires 903 J to raise 1.00 kg of aluminum by 1.00 K.
Material | Specific Heat (J/kg•K) |
Aluminum | 903 |
Brass | 376 |
Carbon | 710 |
Copper | 385 |
Glass | 664 |
Ice | 2060 |
Lead | 130 |
Methanol | 2450 |
Water Vapor | 2020 |
Water (liquid) | 4180 |
Zinc | 388 |
The amount of heat gained or lost by an object when its temperature changes can be calculated by the formula
\begin{align*}Q = mc \Delta t\end{align*},
where \begin{align*}Q\end{align*} is the heat gained or lost, \begin{align*}m\end{align*} is the mass of the object, \begin{align*}c\end{align*} is its specific heat, and \begin{align*}\Delta t\end{align*} is the change in temperature. You should note that the size of a Celsius degree and a Kelvin degree are exactly the same, and therefore \begin{align*}\Delta t\end{align*} is the same whether measured in Celsius or Kelvin.
Example Problem: A 0.500 kg block of zinc is heated from 295 K to 350. K. How much heat was absorbed by the zinc?
Solution: \begin{align*}Q = mc \Delta t = (0.500 \ kg)(388 \ J/kg \cdot K)(350. \ K - 295 \ K) = 10,600 \ J\end{align*}
Example Problem: 845 J of heat are added to a 0.200 kg block of aluminum at a temperature of 312.00 K. How high will the temperature of the aluminum rise?
Solution: \begin{align*}(t_2-t_1)=\frac{Q}{mc}=\frac{845 \ J}{(0.200 \ kg)(903 \ J/kg \cdot K)}=4.68 \ K\end{align*}
\begin{align*}t_2 = t_1 + 4.68 \ K = 312.00 \ K + 4.68 \ K = 316.68 \ K\end{align*}
Summary
- When heat flows into an object, its thermal energy increases and so does its temperature.
- The amount of temperature increase depends on three things: 1) how much heat was added, 2) the size of the object, and 3) the material of which the object is made.
- Each substance has a specific heat, which is the amount of heat necessary to raise one mass unit of that substance by one temperature unit.
- The amount of heat gained or lost by an object when its temperature changes can be calculated by the formula \begin{align*}Q = mc \Delta t\end{align*}.
Practice
Interactive step by step demonstration of how to calculate the specific heat of a material.
http://www.chem.uiuc.edu/webfunchem/specificheat/newSample.htm
Practice problems in specific heat.
http://www.kwanga.net/chemnotes/specific-heat-practice.pdf
Review
- How much heat is absorbed by 60.0 g of copper when it is heated from 20.0°C to 80.0°C?
- A 40.0 kg block of lead is heated from -25°C to 200.°C. How much heat is absorbed by the lead block?
- The cooling system of an automobile motor contains 20.0 kg of water. What is the \begin{align*}\Delta t\end{align*} of the water if the engine operates until 836,000 J of heat have been added to the water?
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Concept Nodes:
- specific heat: The heat required to raise a unit mass of a substance by one unit temperature interval under specified conditions, such as constant pressure: usually measured in joules per kelvin per kilogram.