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Ideal Gas Law

Introduces law based on the Combined Gas Law and Avogadro's Law

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Ideal Gas Law

The ideal gas law can be used to determine the amount of gas present in a system

Credit: User:Masur/Wikimedia Commons
Source: http://commons.wikimedia.org/wiki/File:Gas_cylinder_ammonia.jpg
License: CC BY-NC 3.0

What chemical reactions require ammonia?

There are a number of chemical reactions that require ammonia. In order to carry out the reaction efficiently, we need to know how much ammonia we have for stoichiometric purposes. Using gas laws, we can determine the number of moles present in the tank if we know the volume, temperature, and pressure of the system.

Ideal Gas Law

The combined gas law shows that the pressure of a gas is inversely proportional to volume and directly proportional to temperature. Avogadro’s law shows that volume or pressure is directly proportional to the number of moles of gas. Putting these together leaves us with the following equation:

As with the other gas laws, we can also say that  is equal to a constant. The constant can be evaluated provided that the gas being described is considered to be ideal.

The ideal gas law is a single equation which relates the pressure, volume, temperature, and number of moles of an ideal gas. If we substitute in the variable  for the constant, the equation becomes:

The ideal gas law is conventionally rearranged to look this way, with the multiplication signs omitted:

The variable  in the equation is called the ideal gas constant.

Evaluating the Ideal Gas Constant

The value of , the ideal gas constant, depends on the units chosen for pressure, temperature, and volume in the ideal gas equation. It is necessary to use Kelvin for the temperature and it is conventional to use the SI unit of liters for the volume. However, pressure is commonly measured in one of three units: kPa, atm, or mmHg. Therefore,  can have three different values.

We will demonstrate how  is calculated when the pressure is measured in kPa. Recall that the volume of 1.00 mol of any gas at STP is measured to be 22.414 L. We can substitute 101.325 kPa for pressure, 22.414 L for volume, and 273.15 K for temperature into the ideal gas equation and solve for .

This is the value of  that is to be used in the ideal gas equation when the pressure is given in kPa. Table below shows a summary of this and the other possible values of . It is important to choose the correct value of  to use for a given problem.

Values of the Ideal Gas Constant
Unit of
Unit of Unit of
Unit of Value and unit of
kPa L mol K
atm L mol K
mmHg L mol K

Notice that the unit for  when the pressure is in kPa has been changed to J/K • mol. A kilopascal multiplied by a liter is equal to the SI unit for energy, a joule (J).

 

 

Sample Problem: Ideal Gas Law

What volume is occupied by 3.760 g of oxygen gas at a pressure of 88.4 kPa and a temperature of 19°C? Assume the oxygen is ideal.

Step 1: List the known quantities and plan the problem.

Known

Unknown

In order to use the ideal gas law, the number of moles of O2  must be found from the given mass and the molar mass. Then, use  to solve for the volume of oxygen.

Step 2: Solve.

Rearrange the ideal gas law and solve for .

Step 3: Think about your result.

The number of moles of oxygen is far less than one mole, so the volume should be fairly small compared to molar volume (22.4 L/mol) since the pressure and temperature are reasonably close to standard. The result has three significant figures because of the values for  and . Since a joule (J) = kPa • L, the units cancel correctly, leaving a volume in liters.

 

 

Summary

  • The ideal gas constant is calculated.
  • An example of calculations using the ideal gas law is shown.

Review

  1. Which value of  will you use if the pressure is given in atm?
  2. You are doing a calculation where the pressure is given in mm Hg. You select 8.314 J/K • mol as your value for . Will you get a correct answer?
  3. How would you check that you have chosen the correct value of  for your problem?

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Image Attributions

  1. [1]^ Credit: User:Masur/Wikimedia Commons; Source: http://commons.wikimedia.org/wiki/File:Gas_cylinder_ammonia.jpg; License: CC BY-NC 3.0

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