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Polymerization – Condensation Polymers

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Polymerization – Condensation Polymers

A Different Sound and Feel

Animal gut and silk were used for all guitar strings for centuries until modern technology and changes in musical taste brought about significant changes. There are two major types of guitar strings in use today. Steel strings (first developed around 1900) are found on acoustic and electric guitars. They have a bright, crisp sound that lends itself well to diverse music as jazz, rock and roll, and bluegrass. Nylon strings are a more recent development. During World War II, the silk and animal products needed to manufacture steel guitar strings were not available. Nylon quickly proved to be a more than adequate substitute. Now nylon strings are found on all classical guitars. Their sound is somewhat softer than the steel strings and the tone quality suits that genre of music better.

Polymerization - Condensation Polymers

A condensation polymer is a polymer formed by condensation reactions. Monomers of condensation polymers must contain two functional groups so that each monomer can link up with two other monomers. One type of condensation polymer is called a polyamide. An amide is characterized by the functional group shown below wherein the carbon of a carbonyl group is bonded to the nitrogen of an amine.

Amide

One pair of monomers that can form a polyamide is adipic acid and hexanediamine. Adipic acid is a carboxylic acid with two carboxyl groups on either end of the molecule. Hexanediamine has amino groups on either end of a six-carbon chain. When these molecules react with each other, a molecule of water is eliminated, classifying it as a condensation reaction ( Figure below ).

Nylon synthesis

The polymer that results from the repetition of the condensation reaction is a polyamide called nylon-66. Nylon-66 was first invented in 1935 and has been used in all sorts of products. It and other polyamides are commonly found in fibers and clothing, cooking utensils, fishing line, and carpeting, among many other applications.

Nylon spatula.

Polyester is another common type of condensation polymer. Recall that esters are formed from the reaction of an alcohol with a carboxylic acid. When both the acid and alcohol have two functional groups, the ester is capable of being polymerized. One such polyester is called polyethylene terephthalate (PET) and is formed from the reaction of ethylene glycol with terephthalic acid. The structure of PET is shown below.

PET is used in tires, photographic film, food packaging, and clothing. Polyester fabric is used in permanent-press clothing. Its resistance to wrinkling comes from the cross-linking of the polymer strands.

Summary

  • A polymer condensation reaction is defined.
  • Examples of condensation reactions are shown.
  • Examples of condensation polymers are described.

Practice

Read the material at the link below and answer the following questions:

http://www.amazingwomeninhistory.com/stephanie-kwolek-inventor-kevlar/

  1. Who invented Kevlar and when?
  2. What started the project that led to the development of Kevlar?
  3. What is a major use for Kevlar today?

Review

  1. What is a condensation reaction?
  2. What structural characteristics do the two monomers need to have?
  3. What monomers compose nylon-66?

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