Flexi Says: Changes of state from solid to liquid and from liquid to gas occur when matter gains energy. The energy allows individual molecules to separate and move apart from one another. It takes more energy to bring about these changes of state for polar molecules. Although hydrogen bonds are weak, they add to the energy needed for molecules to move apart from one another, so it takes higher temperatures for these changes of state to occur in polar compounds. This explains why polar compounds have relatively high melting and boiling points.
